Although optical microscopy is a widely used technique across various multidisciplinary fields for inspecting small-scale objects, surfaces or organisms, it faces a significant limitation: the lateral resolution of optical microscopes is fundamentally constrained by light diffraction. Dielectric micro-spheres, however, offer a promising solution to this issue as they are capable of significantly enhancing lateral resolution through extraordinary phenomena, such as a photonic nanojet.Building upon the potential of dielectric micro-spheres, this paper introduces a novel approach for fabricating 3D micro-devices designed to enhance lateral resolution in optical microscopy. The proposed 3D micro-device comprises a modified coverslip and a micro-sphere, facilitating easy handling and integration into any existing optical microscope. To manufacture the device, two advanced femtosecond laser techniques are employed: femtosecond laser ablation and multi-photon lithography. Femtosecond laser ablation was employed to create a micro-hole in the coverslip, which allows light to be focused through this aperture. Multi-photon lithography was used to fabricate a micro-sphere with a diameter of 20 µm, along with a cantilever that positions the above the processed micro-hole and connect it with the coverslip. In this context, advanced processing strategies for multi-photon lithography to produce a micro-sphere with superior surface roughness and almost perfect geometry (λ/8) from a Zr-based hybrid photoresist are demonstrated. The performance of the micro-device was evaluated using Mirau-type coherence scanning interferometry in conjunction with white light illumination at a central wavelength of 600 nm and a calibration grid (Λ = 0.28 µm, h > 50 nm). Here, the 3D micro-device proved to be capable of enhancing lateral resolution beyond the limits achievable with conventional lenses or microscope objectives when used in air. Simultaneously, it maintained the high axial resolution characteristic of Mirau-type coherence scanning interferometry. The results and optical properties of the micro-sphere were analyzed and further discussed through simulations.
The field-of-view (FOV), depth of field, and resolution of conventional microscopes are constrained by each other; therefore, a zoom function is required. Traditional zoom methods lose real-time performance and have limited information throughput, severely limiting their application, especially in three-dimensional dynamic imaging and large-amount or large-size sample scanning. Here, an adaptive multiscale (AMS) imaging mechanism combining the benefits of liquid lenses and multiscale imaging techniques is proposed to realize the functions of fast zooming, wide working distance (WD) range and large FOV on a self-developed AMS microscope. The design principles were revealed. Moreover, a nonuniform-distortion-correction algorithm and a composite patching algorithm were designed to improve image quality. The continuous tunable magnification range of the AMS microscope is from 9× to 18×, with the corresponding FOV diameters and resolution ranging from 2.31 to 0.98 mm and from 161 to 287 line-pairs/mm, respectively. The extended WD range is 0.8 mm and the zoom response time is 38 ms. Experiments demonstrated the advantages of the proposed microscope in pathological sample scanning, thick-sample imaging, microfluidic process monitoring, and the observation of living microorganisms. The proposed microscope is the first step towards zoom multiscale imaging technology and is expected to be applied in life sciences, medical diagnosis, and industrial detection.
One of the challenges in the field of multi-photon 3D laser printing lies in further increasing the print speed in terms of voxels/s. Here, we present a setup based on a 7 × 7 focus array (rather than 3 × 3 in our previous work) and using a focus velocity of about 1 m/s (rather than 0.5 m/s in our previous work) at the diffraction limit (40×/NA1.4 microscope objective lens). Combined, this advance leads to a ten times increased print speed of about 108 voxels/s. We demonstrate polymer printing of a chiral metamaterial containing more than 1.7 × 1012 voxels as well as millions of printed microparticles for potential pharmaceutical applications. The critical high-quality micro-optical components of the setup, namely a diffractive optical element generating the 7 × 7 beamlets and a 7 × 7 lens array, are manufactured by using a commercial two-photon grayscale 3D laser printer.
In this paper, we experimentally demonstrate a non-volatile switchable infrared stealth metafilm based on high temperature resistant metal Molybdenum (Mo) and phase change material Ge2Sb2Te5(GST). By controlling the phase state of GST, the switch between the infrared stealth and the non-stealth states can be realized. Specifically, when the GST is in the amorphous state, the emissivity of the film in the 3−5 μm and 8−14 μm atmospheric window band is suppressed and can realize infrared stealth, together with a high absorption peak of 94% at 6.08 μm, which enables radiative heat dissipation; While for the crystalline state of the GST, the average emissivity is more than 0.7 in the band of 8−14 μm, and the infrared stealth function cannot be realized. When the background temperature is 100°C, the temperature difference between the two samples reaches as high as 28°C under an infrared thermal imager. Therefore, our proposed metafilm can flexibly regulate the infrared thermal radiation of the target so as to realize the switch between the infrared stealth and non-stealth state. We have fabricated the metafilm on both hard and flexible substrates. Our work holds profound significance for the study of dynamic thermal radiation control and it is set to pave the way for the practical implementation of intelligent infrared stealth technology.
A universal method of micro-patterning thin quantum dot films is highly desired by industry to enable the integration of quantum dot materials with optoelectronic devices. Many of the methods reported so far, including specially engineered photoresist or ink-jet printing, are either of poor yield, resolution limited, difficult to scale for mass production, overly expensive, or sacrificing some optical quality of the quantum dots. In our previous work, we presented a dry photolithographic lift-off method for pixelization of solution-processed materials and demonstrated its application in patterning perovskite quantum dot pixels, 10 µm in diameter, to construct a static micro-display. This report presents further development of this method and demonstrates high-resolution patterning (~1 µm diameter), full-scale processing on a 100 mm wafer, and multi-color integration of two different varieties of quantum dots. Perovskite and cadmium-selenide quantum dots were adopted for the experimentation, but the method can be applied to other types of solution-processed materials. We also demonstrate the viability of this method for constructing high-resolution micro-arrays of quantum dot color-convertors by fabricating patterned films directly on top of a blue gallium-nitride LED substrate. The green perovskite quantum dots used for fabrication were synthesized via the room-temperature ligand-assisted reprecipitation method developed by our research group, yielding a photoluminescent quantum yield of 93.6% and full-width half-maximum emission linewidth less than 20 nm. Our results demonstrate the viability of this method for use in scalable manufacturing of high-resolution micro-displays paving the way for improved optoelectronic applications.
Complex field modulation (CFM) has found a plethora of applications in physics, biomedicine, and instrumentation. Among existing methods, superpixel-based CFM has been increasingly featured because of its advantages in high modulation accuracy and its compatibility with high-speed spatial light modulators (SLMs). Nonetheless, the mainstream approach based on binary-amplitude modulation confronts limitations in optical efficiency and dynamic range. To surmount these challenges, we develop binary phase-engraved (BiPE) superpixel-based CFM and implement it using the phase light modulator (PLM)—a new micro-electromechanical system-based SLM undergoing development by Texas Instruments in recent years. Using BiPE superpixels, we demonstrate high-accuracy spatial amplitude and phase modulation at up to 1.44 kHz. To showcase its broad utility, we apply BiPE superpixel-based CFM to beam shaping, high-speed projection, and augmented-reality display.
Advancements in additive manufacturing (AM) are revolutionizing 3D part production, making 3D printing crucial for creating optical devices like lenses and waveguides. This study employs vat photopolymerization (VPP) to fabricate adaptive 4D printed smart Fresnel lenses with photochromic properties using digital light processing (DLP). These lenses are fabricated with precise optical performance and geometric dimensions. Photochromic powders enable dynamic color changes upon UV exposure. The lenses were optically evaluated in both inactive and active states, demonstrating excellent UV and blue light blocking when inactive. Upon UV activation, the lenses darken and absorb parts of the visible light spectrum, with the degree of absorption and color change dependent on the photochromic material and its concentration. The lenses show minimal focal length errors, maintaining high precision and UV responsiveness even at low concentrations. This research highlights the lenses' precision, UV responsiveness, blue light filtering capabilities, and stability after multiple UV exposure cycles. These findings underscore the potential of 4D printing in developing smart optical devices tailored for applications that demand dynamic light modulation and UV filtering, highlighting a combination of innovative manufacturing techniques and functional optics.
Lead halide perovskite quantum dots (QDs) suffer from frequent batch-to-batch inconsistencies and poor reproducibility, resulting in serious non-radiative defect-assisted recombination and Auger recombination. To overcome these challenges, in this study, CsPbBr3 QDs were prepared by designing a novel cesium precursor recipe that involved a combination of dual-functional acetate (AcO−) and 2-hexyldecanoic acid (2-HA) as short-branched-chain ligand: first, AcO− aided in significantly improving the complete conversion degree of cesium salt, enhancing the purity of the cesium precursor from 70.26% to 98.59% with a low relative standard deviation of size distribution and photoluminescence quantum yield (9.02 and 0.82%, respectively) by decreasing the formation of by-products during the reaction, which leads to enhanced homogeneity and reproducibility, especially at room temperature. Second, AcO− can act as a surface ligand to passivate the dangling surface bonds. Furthermore, compared to oleic acid, 2-HA exhibited a stronger binding affinity toward the QDs, further passivated the surface defects, and effectively suppressed biexciton Auger recombination, thereby improving the spontaneous emission rate of the QDs. Consequently, the QDs prepared using this new recipe exhibited a uniform size distribution, a green emission peak at 512 nm, a high photoluminescence quantum yield of 99% with excellent stability, and a narrow emission linewidth of 22 nm. In particular, the optimized QDs exhibited enhanced amplified spontaneous emission (ASE) performance, while the ASE threshold of treated QDs reduced by 70% from 1.8 μJ·cm−2 to 0.54 μJ·cm−2.
In photonic crystal slab (PCS) structures, the bound states in the continuum (BICs) and circularly polarised states (dubbed C-points) are critical topological polarisation singularities in momentum space that have garnered significant attention owing to their novel topological and optical properties. In this study, we engineered a novel PCS imager featuring two C-points with opposite chirality through symmetry breaking, resulting in maximal asymmetric transmission responses characterised by near-unity circular dichroism (CD) values. By harnessing the chiral selectivity of the C-points, a high-CD PCS imager can provide two sets of optical transfer functions (OTFs) to facilitate both edge detection and bright-field imaging. Notably, one set of OTFs was finely tuned to a Lorentzian line shape to achieve perfect edge detection. We developed a multifunctional imaging system by integrating a PCS imager into a traditional optical system. Both theoretical and experimental demonstrations confirmed that this system provides bright-field and edge-enhanced images with micrometer-scale resolution. Furthermore, these two independent functions can be easily switched by altering the circular polarisation state of the light source.
ZnO nanomaterials have become appealing for next-generation micro/nanodevices owing to their remarkable functionality and outstanding performance. However, in-situ, one-step, patterned synthesis of ZnO nanomaterials with small grain sizes and high specific surface areas remains challenging. While breakthroughs in laser-based synthesis techniques have enabled simultaneous growth and patterning of these materials, device integration restrictions owing to pre-prepared laser-absorbing layers remain a severe issue. Herein, we report a single-step femtosecond laser direct writing (FsLDW) method for fabricating ZnO nanomaterial micropatterns with a minimum linewidth of less than 1 μm without requiring laser-absorbing layers. Furthermore, utilizing the grain-size modulation effect of glycerol, we successfully reduced the grain size and addressed the challenges of discontinuity and non-uniform product formation during FsLDW. Using this technique, we successfully fabricated a series of micro-photodetectors with exceptional performance, a switching ratio of 105, and a responsivity of 102 A/W. Notably, the devices exhibited an ultralow dark current of less than 10 pA, more than one order of magnitude lower than the dark current of ZnO photodetectors under the same bias voltage—crucial for enhancing the signal-to-noise ratio and reducing the power consumption of photodetectors. The proposed method could be extended to preparing other metal-oxide nanomaterials and devices, thus providing new opportunities for developing customized, miniaturized, and integrated functional devices.
We experimentally demonstrate ultrafast laser-writing wide-gamut structural colors on TiAlN thin film that is coated on TiN substrate via laser-induced surface oxidation. The experiments involve thorough control over laser parameters, including powers, scanning speeds and pulse durations, to investigate the interplay between these variables and the resulting structural colors. Surface characterization techniques, such as scanning electron microscopy, energy-dispersive x-ray spectroscopy and atomic force microscopy, are employed to analyze the properties of laser-induced oxide layers and their chromatic responses. Our findings indicate that while laser powers and scanning speeds are critical in determining the irradiated dose and the subsequent coloring effects, the pulse duration exerts a distinct influence, particularly at low laser powers as well as slow scanning speeds. Longer pulse durations are found to produce a more significant coloring change despite exhibiting lower oxygen content. This is attributed to the increased surface roughness and deeper oxidation layer achieved with prolonged pulses. We propose two oxidation mechanisms – photo-oxidation and thermal-oxidation – to elucidate the influence of pulse duration on laser coloring effects. These findings not only refine existing paradigms in laser-induced surface coloration but also stimulate further exploration of structural colors’ multifaceted applications across diverse technological contexts.
In this study, a ray tracing model based on the law of reflection in vector form was developed to obtain the design parameters of multipass cells (MPC) with dense spot patterns. Four MPCs with distinct patterns were obtained using an established mathematical model. An MPC with a four-concentric-circle pattern exhibited the longest optical path length (OPL) of approximately 38 m and an optimal ratio of optical path length to volume (RLV) of 13.8 cm-2. A light-induced thermoelastic spectroscopy (LITES)-based methane (CH4) sensor was constructed for the first time using the developed optimal MPC and Raman fiber amplifier (RFA). A novel trapezoidal-tip quartz tuning fork (QTF) was used as the detector to further improve the sensing performance. The CH4-LITES sensor exhibited an excellent linear response to optical power and CH4 concentration. The minimum detection limit (MDL) of the CH4-LITES sensor reached 322 ppb when the output optical power of the RFA was 350 mW. The Allan deviation of the system indicated that the MDL decreased to 59.5 ppb when the average time was increased to 100 s.
Femtosecond laser fabrication technology has been applied to photonic-lantern mode (de)multiplexers owing to its 3D fabrication capability. Current photonic-lantern mode (de)multiplexer designs based on femtosecond laser fabrication technology mostly follow a fibre-type photonic lantern design, which uses trajectory-symmetry structures with non-uniform waveguides for selective mode excitation. However, non-uniform waveguides can lead to inconsistent waveguide transmission and coupling losses. Trajectory-symmetry designs are inefficient for selective-mode excitation. Therefore, we optimised the design using trajectory asymmetry with uniform waveguides and fabricated superior ultrafast laser-inscribed photonic-lantern mode (de)multiplexers. Consistent waveguide transmission and coupling losses (0.1 dB/cm and 0.2 dB/facet, respectively) at 1550 nm were obtained on uniform single-mode waveguides. Based on the trajectory-asymmetry design for photonic-lantern mode (de)multiplexers, efficient mode excitation (
,
, and
) with average insertion losses as low as 1 dB at 1550 nm was achieved, with mode-dependent losses of less than 0.3 dB. The photonic-lantern design was polarisation-insensitive, and the polarisation-determined losses were less than 0.2 dB. Along with polarisation multiplexing realised by fibre-type polarisation beam splitters, six signal channels (
,
,
,
,
, and
), each carrying 42 Gaud/s quadrature phase-shift keying signals, were transmitted through a few-mode fibre for optical transmission. The average insertion loss of the system is less than 5 dB, while its maximum crosstalk with the few-mode fibre is less than −12 dB, leading to a 4-dB power penalty. The findings of this study pave the way for the practical application of 3D integrated photonic chips in high-capacity optical transmission systems.
Lunar sample return missions are crucial for researching the composition and origin of the Moon. In recent decades, several lunar sample return missions have been conducted, yielding abundant and valuable lunar samples. As the latest development in lunar sample returns, the Chang’e-6 mission aimed to implement lunar farside sampling. The shorter time available for sampling requires higher sampling efficiency. In this study, the main factors in the sampling site selection and sampling process are introduced and a vision-based sampling implementation is designed for the Chang’e-6 mission to significantly simplify manual operation while maintaining high sampling quality. By sufficiently leveraging the point cloud data reconstructed from the binocular camera images, autonomous terrain analysis and sample point selection are achieved. A 6D pose estimation pipeline based on point cloud registration provides a robust method for sampler pose measurement, replacing the previous manual fine-tuning process and achieving better accuracy. Owing to the well-analyzed sample points and accurate fine-tuning, the proposed approach demonstrates high accuracy in controlling the scooping depth, while significantly reducing the time cost of the sampling implementation, effectively supporting the Chang’e-6 lunar sample mission.
ISSN 2689-9620 EISSN 2831-4093
Indexed by:
- ESCI
- DOAJ
- Scopus
- Google Scholar
- CNKI
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2021, 2(3): 350-369. doi: 10.37188/lam.2021.024
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2023, 4(4): 519-542. doi: 10.37188/lam.2023.031
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2021, 2(3): 313-332. doi: 10.37188/lam.2021.020
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2021, 2(4): 446-459. doi: 10.37188/lam.2021.028
