Femtosecond 3D-printing offers tantalizing avenues for miniaturization and integration of micro optical systems. Available photoresists, however, restrain their utility in liquid immersion, especially in media with refractive indices larger than n = 1.33, such as glues or biomedical fluids. We present monolithic 3D-printed immersion optics, equipped with compact microfluidic sealing to protect the micro optical device from intrusion of liquid immersion media. We experimentally demonstrate diffraction limited performance in water, silicone-, and immersion oil, for a tailored aspherical-spherical doublet with a numerical aperture of NA = 0.625 and a footprint as small as a single mode optical fiber. Such compact monolithic immersion micro optics yield high potential to advance miniaturization for in situ biomedical sensing and robust coupling between fibers and photonic integrated circuits.

Detecting electrolyte leakage is an effective early warning approach for abnormal faults in lithium-ion batteries (LIBs) and can help mitigate safety risks such as fires and explosions. However, detecting electrolyte leakage in the early stages of LIB faults presents a significant challenge, as leaks in LIBs produce volatile organic compounds (VOCs) at parts per million levels that are difficult to detect using conventional VOC sensors. Here, an effective LIB VOC sensor using micro-nano optical fibres (MNFs) has been developed for the first time, coated with an in situ self-assembled zeolitic imidazolate framework-8 (ZIF-8) membrane as an electrolyte-sensitive layer. The abundance of pores in ZIF-8 is excellent for adsorbing a variety of VOCs, including diethyl carbonate, ethyl methyl carbonate, dimethyl carbonate, and propylene carbonate. The MNFs possess high refractive index sensitivity, enhancing the online monitoring of electrolytes. MNFs with a diameter of approximately 7 μm were assembled with four-cycle ZIF-8 of approximately 500 nm thickness, as the fabricated sensor. Through wavelength demodulation, the LIB sensor demonstrated high sensitivity, detecting 43.6 pm/ppm of VOCs and exhibiting rapid response and recovery times of typically within 10 min and 23 s, respectively, as well as a low theoretical detection limit of 2.65 ppm for dimethyl carbonate vapor with excellent reversibility. The first on-site verification of online LIB leakage monitoring demonstrated that the sensor achieved a 35 h early warning prior to full-load leakage, thus exhibiting promising prospects for applications in scenarios such as car batteries.

Deformable mirrors are essential dynamic wavefront compensation. Among the various types of deformable mirrors with different actuation mechanisms, the unimorph piezoelectric deformable mirror (UPDM) offers distinct advantages owing to its compact size and low cost. The two most critical challenges in UPDM are electrode fabrication and deformation control. This study proposes an integrated electrode fabrication and sensorless feedback control scheme for UPDM, which simplifies the manufacturing process and enhances its performance. The electrode array is created using silkscreen printing combined with flexible printed circuit board technology, integrating electrode fabrication and electrical connection into a single step. The desired mirror deformation is achieved by introducing a closed-loop direct deformation control method based on piezoelectric self-sensing. The feedback mechanism utilizes the local strain-induced charge generated by the piezoelectric plate, effectively addressing the nonlinear behavior of the piezoelectric material. Experimental results confirm the feasibility and effectiveness of the proposed method, with the maximum relative error in the steady state phase remaining below 2%.

Melanoma, a highly malignant and complex form of cancer, has increased in global incidence, with a growing number of new cases annually. Active targeting strategies, such as leveraging the α-melanocyte-stimulating hormone (αMSH) and its interaction with the melanocortin 1 receptor (MC1R) overexpressed in melanoma cells, enhance the concentration of therapeutic agents at tumor sites. For instance, targeted delivery of plasmonic light-sensitive agents and precise hyperthermia management provide an effective, minimally invasive treatment for tumors. In this work, we present a comparative study on targeted photothermal therapy (PTT) using plasmonic gold nanorods (Au NRs) as a robust and safe nanotool to reveal how key treatment parameters affect therapy outcomes. Using an animal model (B16-F10) of melanoma tumors, we compare the targeting abilities of Au NRs modified with two different MC1R agonists, either closely mimicking the αMSH sequence or providing a superior functionalization extent of Au NRs (4.5% (w/w) versus 1.8% (w/w)), revealing 1.6 times better intratumoral localization. Following theoretical and experimental assessments of the heating capabilities of the developed Au NRs under laser irradiation in either the femtosecond (FS)- or nanosecond (NS)- pulsed regime, we perform targeted PTT employing two types of peptide-modified Au NRs and compare therapeutic outcomes revealing the most appropriate PTT conditions. Our investigation reveals greater heat release from Au NRs under irradiation with FS laser, due to the relaxation rates of the electron and phonon temperatures dissipating in the surrounding, which correlates with a more pronounced 17.6 times inhibition of tumor growth when using FS-pulsed regime.

In this paper, we experimentally demonstrate a non-volatile switchable infrared stealth metafilm based on high temperature resistant metal Molybdenum (Mo) and phase change material Ge₂Sb₂Te₅(GST). By controlling the phase state of GST, the switch between the infrared stealth and the non-stealth states can be realized. Specifically, when the GST is in the amorphous state, the emissivity of the film in the 3−5 μm and 8−14 μm atmospheric window band is suppressed and can realize infrared stealth, together with a high absorption peak of 94% at 6.08 μm, which enables radiative heat dissipation; While for the crystalline state of the GST, the average emissivity is more than 0.7 in the band of 8−14 μm, and the infrared stealth function cannot be realized. When the background temperature is 100°C, the temperature difference between the two samples reaches as high as 28°C under an infrared thermal imager. Therefore, our proposed metafilm can flexibly regulate the infrared thermal radiation of the target so as to realize the switch between the infrared stealth and non-stealth state. We have fabricated the metafilm on both hard and flexible substrates. Our work holds profound significance for the study of dynamic thermal radiation control and it is set to pave the way for the practical implementation of intelligent infrared stealth technology.

ZnO nanomaterials have become appealing for next-generation micro/nanodevices owing to their remarkable functionality and outstanding performance. However, in-situ, one-step, patterned synthesis of ZnO nanomaterials with small grain sizes and high specific surface areas remains challenging. While breakthroughs in laser-based synthesis techniques have enabled simultaneous growth and patterning of these materials, device integration restrictions owing to pre-prepared laser-absorbing layers remain a severe issue. Herein, we report a single-step femtosecond laser direct writing (FsLDW) method for fabricating ZnO nanomaterial micropatterns with a minimum linewidth of less than 1 μm without requiring laser-absorbing layers. Furthermore, utilizing the grain-size modulation effect of glycerol, we successfully reduced the grain size and addressed the challenges of discontinuity and non-uniform product formation during FsLDW. Using this technique, we successfully fabricated a series of micro-photodetectors with exceptional performance, a switching ratio of 10⁵, and a responsivity of 10² A/W. Notably, the devices exhibited an ultralow dark current of less than 10 pA, more than one order of magnitude lower than the dark current of ZnO photodetectors under the same bias voltage—crucial for enhancing the signal-to-noise ratio and reducing the power consumption of photodetectors. The proposed method could be extended to preparing other metal-oxide nanomaterials and devices, thus providing new opportunities for developing customized, miniaturized, and integrated functional devices.

Accelerometers are crucial sensors that measure acceleration resulting from motion or vibration. Compared with their electromechanical counterparts, optical accelerometers are widely regarded as the most promising technology for high-requirement applications. However, compact integration of various optical and mechanical components to create a miniature optomechanical microsystem for acceleration sensing remains a challenge. In this study, we present a miniature optical fiber accelerometer based on a 3D microprinted ferrule-top Fabry–Pérot (FP) microinterferometer. In-situ 3D microprinting technology was developed to directly print a sub-millimeter-scale 3D proof mass/thin-film reflector-integrated FP microinterferometer on the inherently light-coupled end face of a fiber optic ferrule. Experimental results demonstrate that the optical fiber accelerometer has a flat response over a bandwidth of 2 to 3 kHz and its noise equivalent acceleration is 62.45 μg/Hz under 1-g acceleration at 2 kHz. This ultracompact optical fiber interferometric accelerometer offers several distinct advantages, including immunity to electromagnetic interference, remote-sensing capability, and high customizability, making it highly promising for a variety of stringent acceleration-monitoring applications.

Quantum dots, semiconductor crystals with nanometer-scale dimensions, exhibit adjustable chemical, electrical, and optical characteristics owing to the quantum confinement effect. However, achieving high-quality quantum dots necessitates simultaneous attainment of crystalline integrity within their cores, uniformity in size and shape, as well as effective surface passivation with charge transport functionality—challenges persist regardless of the chosen method. Here, we introduce a novel approach for synthesizing quantum-dot/perovskite heterocrystals: the Colloidal Quantum Dot-Oriented Attachment to Perovskite Single Crystal (CQD-OA-PSC) method. This method involves optimizing quantum dot growth through chemical colloidal synthesis methods, followed by their oriented attachment onto macroscopic perovskite single crystals with impeccable lattice alignment. Consequently, the CQD-OA-PSC method amalgamates the strengths of wet chemical colloidal synthesis methods and solution-based epitaxial growth, offering precise control over quantum dot size, morphology, and structure while leveraging charge transport functionality conferred by the matrix crystal. High-resolution transmission electron microscopy confirms matched lattice orientations between the perovskite matrix and quantum dots. This approach promises to yield high-quality quantum dots perovskite heterocrystals with controlled size, morphology, and optoelectronic properties, thereby holding significant potential for advancing the development of efficient optoelectronic devices.