In photonic crystal slab (PCS) structures, the bound states in the continuum (BICs) and circularly polarised states (dubbed C-points) are critical topological polarisation singularities in momentum space that have garnered significant attention owing to their novel topological and optical properties. In this study, we engineered a novel PCS imager featuring two C-points with opposite chirality through symmetry breaking, resulting in maximal asymmetric transmission responses characterised by near-unity circular dichroism (CD) values. By harnessing the chiral selectivity of the C-points, a high-CD PCS imager can provide two sets of optical transfer functions (OTFs) to facilitate both edge detection and bright-field imaging. Notably, one set of OTFs was finely tuned to a Lorentzian line shape to achieve perfect edge detection. We developed a multifunctional imaging system by integrating a PCS imager into a traditional optical system. Both theoretical and experimental demonstrations confirmed that this system provides bright-field and edge-enhanced images with micrometer-scale resolution. Furthermore, these two independent functions can be easily switched by altering the circular polarisation state of the light source.
One of the challenges in the field of multi-photon 3D laser printing lies in further increasing the print speed in terms of voxels/s. Here, we present a setup based on a 7 × 7 focus array (rather than 3 × 3 in our previous work) and using a focus velocity of about 1 m/s (rather than 0.5 m/s in our previous work) at the diffraction limit (40×/NA1.4 microscope objective lens). Combined, this advance leads to a ten times increased print speed of about 108 voxels/s. We demonstrate polymer printing of a chiral metamaterial containing more than 1.7 × 1012 voxels as well as millions of printed microparticles for potential pharmaceutical applications. The critical high-quality micro-optical components of the setup, namely a diffractive optical element generating the 7 × 7 beamlets and a 7 × 7 lens array, are manufactured by using a commercial two-photon grayscale 3D laser printer.
Holographic patterns that integrate printings and holograms into a single device have received extensive attention in optical security owing to their attractive aesthetics and concealment. However, the sophisticated structures of metasurface-based optical devices require a time-consuming fabrication process, hindering the practical application of holographic patterns in optical security. In this study, a novel double-layer holographic pattern that employs simple microholes and microvoids as optical modulation units is designed and experimentally demonstrated. The two layers of the structure arrays are synchronously processed in a transparent material through a single serial-stitching of dynamic 3D spatially modulated femtosecond pulses that are proposed for the rapid fabrication of large-area multi-layered patterns. The fabricated holographic pattern appears as a dynamic grayscale image under white light incident at different angles and projects encoded holographic images under laser illumination. By transforming microholes into microcraters by ultrasonic treatment, the reconfiguration of the holographic pattern can be realized based on refractive index modulation using liquid immersion. The proposed reconfigurable holographic patterns with simple structures and visible sizes enable the recoding of multiple pieces of information, making them practical optical security elements with a wide range of applications in anti-counterfeiting and information encryption.
X-ray scintillation detectors play an irreplaceable role in medical imaging, security inspections, and nondestructive detection. Recently, all-inorganic lead-free metal halide scintillators have attracted attention for addressing the drawbacks of lead-halide perovskites, such as severe self-absorption and toxicity. Nevertheless, high-resolution, flexible, and cost-effective lead-free scintillators are desirable for X-ray imaging applications. In this study, we designed a zero-dimensional hybrid cuprous halide, (MTP)2Cu4I6 (MTP+ represents [C19H18P]+), and synthesized single crystals. (MTP)2Cu4I6 shows intense yellow emission (618 nm) and a large Stokes shift of 185 nm, almost eliminating the effect of self-absorption. As a result, (MTP)2Cu4I6 exhibited a near-unity photoluminescence quantum yield (99.9%) with a light yield of 43800 photons per megaelectron volt. Moreover, (MTP)2Cu4I6 demonstrates an impressive detection performance with a fast response time of 2.18 μs, a good linear response ranging from 0.038 μGyair s-1 to 53.4 μGyair s-1, and a low detection limit of 37.6 nGyair s-1. In a conceptual experiment, large-area flexible (MTP)2Cu4I6/polydimethylsiloxane (PDMS) scintillation films were fabricated to investigate their X-ray imaging performance. The (MTP)2Cu4I6/PDMS film exhibits a high-spatial resolution of 10.2 lp mm-1 when the modulation transfer function is 0.2 and superior flexible detection performance. The short lifetime, high-light yield, low toxicity, and low cost of (MTP)2Cu4I6 facilitate the development of next-generation X-ray scintillators.

ISSN 2689-9620 EISSN 2831-4093
Indexed by:
- ESCI (IF 10.6)
- DOAJ
- Scopus
- Google Scholar
- CNKI
- CSCD
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2023, 4(2): 143-167. doi: 10.37188/lam.2023.011
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2021, 2(3): 350-369. doi: 10.37188/lam.2021.024
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2023, 4(4): 519-542. doi: 10.37188/lam.2023.031
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2021, 2(1): 59-83. doi: 10.37188/lam.2021.005
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2021, 2(3): 313-332. doi: 10.37188/lam.2021.020